A doubly end-on azido-bridged trinuclear Cu(II) complex

Synthesis, spectral and DFT functional studies

Amitabha Datta, Kuheli Das, Wen Yen Huang, Jui-Hsien Huang, Fu Xing Liao, Ching-Han Hu

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L) (N3)3(CH3OH)]2, (LH = [(CH 3)2NCH2CH2N=CHC6H 3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.

Original languageEnglish
Pages (from-to)140-143
Number of pages4
JournalJournal of Chemical Research
Volume35
Issue number3
DOIs
Publication statusPublished - 2011 Mar 1

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Discrete Fourier transforms
Paramagnetic resonance
Single crystals
Ions
X rays
Molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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abstract = "A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L) (N3)3(CH3OH)]2, (LH = [(CH 3)2NCH2CH2N=CHC6H 3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.",
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A doubly end-on azido-bridged trinuclear Cu(II) complex : Synthesis, spectral and DFT functional studies. / Datta, Amitabha; Das, Kuheli; Huang, Wen Yen; Huang, Jui-Hsien; Liao, Fu Xing; Hu, Ching-Han.

In: Journal of Chemical Research, Vol. 35, No. 3, 01.03.2011, p. 140-143.

Research output: Contribution to journalArticle

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AU - Datta, Amitabha

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