A doubly end-on azido-bridged trinuclear Cu(II) complex: Synthesis, spectral and DFT functional studies

Amitabha Datta, Kuheli Das, Wen Yen Huang, Jui Hsien Huang, Fu Xing Liao, Ching Han Hu

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2 Citations (Scopus)

Abstract

A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L) (N3)3(CH3OH)]2, (LH = [(CH 3)2NCH2CH2N=CHC6H 3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.

Original languageEnglish
Pages (from-to)140-143
Number of pages4
JournalJournal of Chemical Research
Volume35
Issue number3
DOIs
Publication statusPublished - 2011 Mar 1

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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