Abstract
Sulfated zirconia is able to effectively catalyze the reaction between aniline and trimethyl orthoformate to produce formamidine with a product yield of 97% at 313K. N-phenylformimidate is proposed as the reaction intermediate, which reacts further with aniline to produce formamidine. Less degree of acid sites poisoning by the reaction mixture due to the weaker acidity of sulfated zirconia as well as its mesoporosity seem to play important role in this catalyzed reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 135-140 |
| Number of pages | 6 |
| Journal | Catalysis Letters |
| Volume | 104 |
| Issue number | 3-4 |
| DOIs | |
| Publication status | Published - 2005 Nov 1 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
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A convenient preparation method for synthesizing formamidine utilizing sulfated zirconia. / Lin, Chiu Hsun; Tsai, Chih Hsiang; Chang, Han Chung.
In: Catalysis Letters, Vol. 104, No. 3-4, 01.11.2005, p. 135-140.Research output: Contribution to journal › Article
TY - JOUR
T1 - A convenient preparation method for synthesizing formamidine utilizing sulfated zirconia
AU - Lin, Chiu Hsun
AU - Tsai, Chih Hsiang
AU - Chang, Han Chung
PY - 2005/11/1
Y1 - 2005/11/1
N2 - Sulfated zirconia is able to effectively catalyze the reaction between aniline and trimethyl orthoformate to produce formamidine with a product yield of 97% at 313K. N-phenylformimidate is proposed as the reaction intermediate, which reacts further with aniline to produce formamidine. Less degree of acid sites poisoning by the reaction mixture due to the weaker acidity of sulfated zirconia as well as its mesoporosity seem to play important role in this catalyzed reaction.
AB - Sulfated zirconia is able to effectively catalyze the reaction between aniline and trimethyl orthoformate to produce formamidine with a product yield of 97% at 313K. N-phenylformimidate is proposed as the reaction intermediate, which reacts further with aniline to produce formamidine. Less degree of acid sites poisoning by the reaction mixture due to the weaker acidity of sulfated zirconia as well as its mesoporosity seem to play important role in this catalyzed reaction.
UR - http://www.scopus.com/inward/record.url?scp=26844573865&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=26844573865&partnerID=8YFLogxK
U2 - 10.1007/s10562-005-7942-z
DO - 10.1007/s10562-005-7942-z
M3 - Article
AN - SCOPUS:26844573865
VL - 104
SP - 135
EP - 140
JO - Catalysis Letters
JF - Catalysis Letters
SN - 1011-372X
IS - 3-4
ER -