A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Hon Man Lee, Tao Jiang, Edwin D. Stevens, Steven P. Nolan

Research output: Contribution to journal › Article

159 Citations (Scopus)

Abstract

The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)2]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.

Original languageEnglish
Pages (from-to)1255-1258
Number of pages4
JournalOrganometallics
Volume20
Issue number6
DOIs
Publication statusPublished - 2001 Mar 19

Fingerprint

Bearings (structural)
Iridium
Alkenes
carbenes
iridium
imidazoles
alkenes
Atmospheric pressure
Hydrogenation
hydrogenation
Hydrogen
atmospheric pressure
Ligands
catalysts
ligands
Catalysts
room temperature
hydrogen
Temperature
carbene

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Lee, Hon Man ; Jiang, Tao ; Stevens, Edwin D. ; Nolan, Steven P. / A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst. In: Organometallics. 2001 ; Vol. 20, No. 6. pp. 1255-1258.
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Lee, HM, Jiang, T, Stevens, ED & Nolan, SP 2001, 'A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst', Organometallics, vol. 20, no. 6, pp. 1255-1258. https://doi.org/10.1021/om000990x

A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst. / Lee, Hon Man; Jiang, Tao; Stevens, Edwin D.; Nolan, Steven P.

In: Organometallics, Vol. 20, No. 6, 19.03.2001, p. 1255-1258.

Research output: Contribution to journal › Article

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AU - Lee, Hon Man

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AU - Nolan, Steven P.

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AB - The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)2]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.

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Lee HM, Jiang T, Stevens ED, Nolan SP. A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst. Organometallics. 2001 Mar 19;20(6):1255-1258. https://doi.org/10.1021/om000990x

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