A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Hon Man Lee; Tao Jiang; Edwin D. Stevens; Steven P. Nolan

doi:10.1021/om000990x

A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Hon Man Lee, Tao Jiang, Edwin D. Stevens, Steven P. Nolan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

163 Citations (Scopus)

Abstract

The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF₆ (2) has been synthesized by reaction of [Ir(cod)(py)₂]PF₆ with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.

Original language	English
Pages (from-to)	1255-1258
Number of pages	4
Journal	Organometallics
Volume	20
Issue number	6
DOIs	https://doi.org/10.1021/om000990x
Publication status	Published - 2001 Mar 19

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000990x

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title = "A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst",

abstract = "The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)2]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.",

author = "Lee, {Hon Man} and Tao Jiang and Stevens, {Edwin D.} and Nolan, {Steven P.}",

year = "2001",

month = mar,

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AU - Jiang, Tao

AU - Stevens, Edwin D.

AU - Nolan, Steven P.

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AB - The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)2]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.

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