A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Hon Man Lee; Tao Jiang; Edwin D. Stevens; Steven P. Nolan

doi:10.1021/om000990x

A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Hon Man Lee, Tao Jiang, Edwin D. Stevens, Steven P. Nolan

Department of Chemistry

Research output: Contribution to journal › Article

159 Citations (Scopus)

Abstract

The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF₆ (2) has been synthesized by reaction of [Ir(cod)(py)₂]PF₆ with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.

Original language	English
Pages (from-to)	1255-1258
Number of pages	4
Journal	Organometallics
Volume	20
Issue number	6
DOIs	https://doi.org/10.1021/om000990x
Publication status	Published - 2001 Mar 19

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All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Lee, H. M., Jiang, T., Stevens, E. D., & Nolan, S. P. (2001). A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst. Organometallics, 20(6), 1255-1258. https://doi.org/10.1021/om000990x

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abstract = "The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)2]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen.",

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Access to Document

10.1021/om000990x