{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate

Amitabha Datta, Jui Hsien Huang, Shiann Cherng Sheu

Research output: Contribution to journalArticle

Abstract

In the title complex, [Ni(C17H16N2O5)]·2H2O, the NiII ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O - H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed.

Original languageEnglish
Pages (from-to)m559-m560
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number10
DOIs
Publication statusPublished - 2013 Oct 1

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Nickel
nickel
Atoms
atoms
Metals
Schiff Bases
rings
metals
imines
Conformations
Hydrogen bonds
Ligands
Ions
hydrogen bonds
Crystals
ligands
Molecules
Geometry
Water
geometry

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate",
abstract = "In the title complex, [Ni(C17H16N2O5)]·2H2O, the NiII ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O - H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed.",
author = "Amitabha Datta and Huang, {Jui Hsien} and Sheu, {Shiann Cherng}",
year = "2013",
month = "10",
day = "1",
doi = "10.1107/S1600536813026007",
language = "English",
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pages = "m559--m560",
journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
number = "10",

}

{5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate. / Datta, Amitabha; Huang, Jui Hsien; Sheu, Shiann Cherng.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 69, No. 10, 01.10.2013, p. m559-m560.

Research output: Contribution to journalArticle

TY - JOUR

T1 - {5,5′-Dihydroxy-2,2′-[(2-hydroxypropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) dihydrate

AU - Datta, Amitabha

AU - Huang, Jui Hsien

AU - Sheu, Shiann Cherng

PY - 2013/10/1

Y1 - 2013/10/1

N2 - In the title complex, [Ni(C17H16N2O5)]·2H2O, the NiII ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O - H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed.

AB - In the title complex, [Ni(C17H16N2O5)]·2H2O, the NiII ion is four-coordinated by two azomethine N and two phenolato O atoms of the tetradentate Schiff base ligand in a slightly distorted square-planar geometry. In the six-membered ring containing the metal, the azomethine N atoms and the three C atoms of the connecting 1,3-diaminopropane-2-ol, all atoms except the metal are disordered over two sets of sites with an occupacy ratio of 0.566 (3):0.434 (3). The central C atom of the major component is significantly out of the mean plane of the remaing atoms while the conformation of this ring in the minor component is noticeably different. In the crystal, O - H⋯O hydrogen bonds involving the lattice water molecules and the hydroxy groups are observed.

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