1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

Chuang Yi Liao; Hon Man Lee

doi:10.1107/S1600536811048410

1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

Chuang Yi Liao, Hon Man Lee

Department of Chemistry

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

In the title compound, C₁₉H₁₉N₄O ₂ ⁺·Cl^-·C₂H ₃N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

Original language	English
Pages (from-to)	o3362
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811048410
Publication status	Published - 2011 Dec 1

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Liao, C. Y., & Lee, H. M. (2011). 1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate. Acta Crystallographica Section E: Structure Reports Online, 67(12), o3362. https://doi.org/10.1107/S1600536811048410

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title = "1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate",

abstract = "In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.",

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N2 - In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

AB - In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

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