1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

Chuang Yi Liao; Hon Man Lee

doi:10.1107/S1600536811048410

1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

Chuang Yi Liao, Hon Man Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In the title compound, C₁₉H₁₉N₄O ₂ ⁺·Cl^-·C₂H ₃N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

Original language	English
Pages (from-to)	o3362
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811048410
Publication status	Published - 2011 Dec

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536811048410

Fingerprint Dive into the research topics of '1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate'. Together they form a unique fingerprint.

Cite this

@article{272c786b2fee48058e5ce4b03ea9da73,

title = "1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate",

abstract = "In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.",

author = "Liao, {Chuang Yi} and Lee, {Hon Man}",

year = "2011",

month = dec,

doi = "10.1107/S1600536811048410",

language = "English",

volume = "67",

pages = "o3362",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - 1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate

AU - Liao, Chuang Yi

AU - Lee, Hon Man

PY - 2011/12

Y1 - 2011/12

N2 - In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

AB - In the title compound, C19H19N4O 2 +·Cl-·C2H 3N, the dihedral angle between the two phenyl rings is 69.57 (8)°while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent molecules into a two-dimensional hydrogen-bonded network parallel to (001); an intramolecular C-H⋯O hydrogen bond is also observed.

UR - http://www.scopus.com/inward/record.url?scp=83155190439&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=83155190439&partnerID=8YFLogxK

U2 - 10.1107/S1600536811048410

DO - 10.1107/S1600536811048410

M3 - Article

C2 - 22199856

AN - SCOPUS:83155190439

VL - 67

SP - o3362

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 12

ER -