1,2-Eliminations in a novel reductive coupling of nitroarenes to give azoxy arenes by sodium bis(trimethylsilyl)amide

Ru Hwu Jih; Asish R. Das; Wei Yang Chia; Jiann Jyh Huang; Ming Hua Hsu

doi:10.1021/ol050924x

1,2-Eliminations in a novel reductive coupling of nitroarenes to give azoxy arenes by sodium bis(trimethylsilyl)amide

Ru Hwu Jih, Asish R. Das, Wei Yang Chia, Jiann Jyh Huang, Ming Hua Hsu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

(Chemical Equation Presented) Symmetric azoxy arenes were successfully prepared in one step from 2 equiv of the corresponding nitroarenes by use of sodium bis-(trimethylsilyl)amide as the deoxygenating agents in THF at 150°C in a sealed tube.

Original language	English
Pages (from-to)	3211-3214
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	15
DOIs	https://doi.org/10.1021/ol050924x
Publication status	Published - 2005 Jul 21

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol050924x

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title = "1,2-Eliminations in a novel reductive coupling of nitroarenes to give azoxy arenes by sodium bis(trimethylsilyl)amide",

abstract = "(Chemical Equation Presented) Symmetric azoxy arenes were successfully prepared in one step from 2 equiv of the corresponding nitroarenes by use of sodium bis-(trimethylsilyl)amide as the deoxygenating agents in THF at 150°C in a sealed tube.",

author = "Jih, {Ru Hwu} and Das, {Asish R.} and Chia, {Wei Yang} and Huang, {Jiann Jyh} and Hsu, {Ming Hua}",

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AU - Das, Asish R.

AU - Chia, Wei Yang

AU - Huang, Jiann Jyh

AU - Hsu, Ming Hua

PY - 2005/7/21

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AB - (Chemical Equation Presented) Symmetric azoxy arenes were successfully prepared in one step from 2 equiv of the corresponding nitroarenes by use of sodium bis-(trimethylsilyl)amide as the deoxygenating agents in THF at 150°C in a sealed tube.

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